| Bayer 04 Leverkusen | v | Paris Saint Germain | BayArena | 22:45 | |
| Manchester City | v | Barcelona | Etihad Stadium | 22:45 |
| Wednesday 19 February 2014 |
| Milan | v | Atlético de Madrid | Giuseppe Meazza | 22:45 | |
| Arsenal | v | FC Bayern München | Emirates Stadium | 22:45 |
| Tuesday 25 February 2014 |
| Zenit St Petersburg | v | Borussia Dortmund | Petrovski Stadium | 20:00 | |
| Olympiakos | v | Manchester United | Karaiskaki Stadium | 22:45 |
| Wednesday 26 February 2014 |
| FC Schalke 04 | v | Real Madrid | VELTINS-Arena | 22:45 | |
| Galatasaray | v | Chelsea | Türk Telekom Arena | 22:45 |
